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Slip-Driven B1-B2 Phase Transition in Shock-Compressed KCl
1The Peac Institute of Multiscale Sciences, Chengdu, Sichuan, People's Republic of China.
Abstract:
The mechanisms, pathways, and driving force for the classical B1-B2 transitions have long been elusive. Here, we conduct ultrafast x-ray diffraction measurements and systematic atomistic simulations of single-crystal KCl under shock compression and establish a unified model for the B1-B2 transition in KCl. The transition proceeds via resolved-shear-stress-driven slip through two generalized transition pathways, yielding two generalized B1-B2 orientation relationships. Resolved-shear-stress-driven slip is potentially a common mechanism for general B1-B2 transitions.
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