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Updated: Sep 30, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Liquid-Vapor Transition in a Model of a Continuum Particle System with Finite-Range Modified Kac Pair Potential
Qidong He1, Ian Jauslin1, Joel Lebowitz1,2
1Department of Mathematics, Rutgers University, New Brunswick, New Jersey, USA.
Abstract:
We prove the existence of a phase transition in dimension in a continuum particle system interacting with a pair potential containing a modified attractive Kac potential of range , with . This transition is "close", for small positive , to the one proved previously by Lebowitz and Penrose in the van der Waals limit . It is of the type of the liquid-vapor transition observed when a fluid, like water, heated at constant pressure, boils at a given temperature. Previous results on phase transitions in continuum systems with stable potentials required the use of unphysical four-body interactions or special symmetries between the liquid and vapor. The pair interaction we consider is obtained by partitioning space into cubes of volume , and letting the Kac part of the pair potential be uniform in each cube and act only between adjacent cubes. The "short-range" part of the pair potential is quite general (in particular, it may or may not include a hard core), but restricted to act only between particles in the same cube. Our setup, the "boxed particle model", is a special case of a general "spin" system, for which we establish a first-order phase transition using reflection positivity and the Dobrushin-Shlosman criterion.
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