Heterogeneous g-C3N4/Pd metallaphotocatalysis for mild C(sp3)-Cl bond activation in α-chloro carbonyl compounds
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Updated: Oct 16, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Qiuxia Zhang1, Jiancheng Yang1, Yingying Wei1
1College of Chemistry, Zhengzhou University, Zhengzhou, Henan, 450001, China. bxyuan@zzu.edu.cn.
Abstract:
Photoinduced electron transfer from g-C3N4 to Pd generates electron-rich Pd species that facilitate challenging C(sp3)-Cl activation in α-chlorocarbonyl compounds. The heterogeneous metallaphotocatalytic system enables visible-light-driven Suzuki-Miyaura coupling under mild aqueous conditions using a recyclable catalyst.
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