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Published on: December 27, 2018
Barbier Polymerization-Induced Emission toward Organophosphorus-Containing Clusteroluminescent Polymer with
Hong-Min Du1, Xi-Yao Gu1, Wen-Ming Wan1
1Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental and Resource Sciences, Fujian Normal University, Fuzhou, 350007, People's Republic of China.
Abstract:
Stimuli-responsive luminescent polymers hold great promise for smart materials, which, however, suffer from complicated synthetic procedures involving synthesis of stimuli-responsive moiety, luminescent moiety and the polymer mainchain separately. Herein, we report a one-pot Barbier polymerization-induced emission strategy to fabricate a stimuli-responsive clusteroluminescent organophosphorus-containing polymer with intriguing aggregation-induced emission and photochromic characteristics, involving synchronous C-C and C-P bonds formation. An efficient polymeric ligand for a nickel-catalyzed Kumada reaction and stimuli-responsive pigment applications are demonstrated as well. This work therefore provides a versatile strategy for the design of a stimuli-responsive clusteroluminescent polymer.
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