Electrophoretic Motion of Two Spherical Particles with Thick Double Layers

The electrophoretic mobilities of two interacting spheres are calculated numerically for arbitrary values of the double-layer thickness. A general formula for the electrophoretic translational and angular velocities of N interacting particles is derived for low-zeta-potential conditions. The present calculation complements the well-studied case of thin double layers. The results are compared with recent reflection calculations and are used to compute the O(phi) contribution to the electrophoretic mobility of a suspension. Particle interactions can be significant for values of the scaled particle radius kappaa