Related Experiment Videos
Solid state NMR sideband shape simulations for any spinning angle and speed. First order calculation of residual
1Departamento de Química Analítica, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario, Argentina. aolivier@fbioyf.unr.edu.ar
Solid State Nuclear Magnetic Resonance
|February 24, 1998
Abstract:
A simple procedure is described which can be used to simulate solid state NMR sideband shapes for samples rotating at any angle and speed, when a combination of chemical shift anisotropy and dipolar coupling between spin-1/2 and quadrupolar nuclei occurs. The use of Herzfeld-Berger equations for computing individual sideband intensities is coupled to first order perturbation calculation of dipolar coupling effects. The present method can be easily and efficiently implemented on a desktop computer (source code is provided).