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Trans-cis amide bond isomerization in fulleroprolines
A Bianco1, V Lucchini, M Maggini
1Centro Meccanismi di Reazioni Organiche, CNR, Dipartimento di Chimica Organica, Università di Padova, Italy.
Abstract:
The 1H NMR study of fulleroproline derivative Ac-Fpr-OtBu and its Pro analogue Ac-L-Pro-OtBu over a range of temperatures in toluene-d8 solution has enabled the comparison of their equilibrium and activation parameters for the trans/cis interconversion around the amide partial double bond.