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Synthesis of a jojoba bean disaccharide
A Kornienko1, G Marnera, M d'Alarcao
1Department of Chemistry, Tufts University, Medford, MA 02155, USA.
Carbohydrate Research
|October 30, 1998
Abstract:
A synthesis of the disaccharide recently isolated from jojoba beans, 2-O-alpha-D-galactopyranosyl-D-chiro-inositol, has been achieved. The suitably protected chiro-inositol unit was prepared by an enantiospecific synthesis from L-xylose utilizing SmI2-mediated pinacol coupling as a key step.
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