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Updated: May 31, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

有機金属 σ 複合体の固体中のC-C 活性化

Adrian B Chaplin1, Jennifer C Green, Andrew S Weller

  • 1Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QR, UK.

Journal of the American Chemical Society
|July 9, 2011
PubMed
まとめ

研究者は,新しいイリジウムC-Cシグマ複合体を合成しました. このユニークな化合物は,固体状態で可逆的なC-C結合活性化を示し,異なるイリジウムの酸化状態の間の温度に依存する均衡を形成します.

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