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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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レドックス・スイッチブル・デイジー・チェーン・ロタキサンは,ラジカル-ラジカル相互作用によって誘発される

Carson J Bruns1, Marco Frasconi, Julien Iehl

  • 1Department of Chemistry ‡Department of Materials Science and Engineering §Department of Medicine Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208, United States.

Journal of the American Chemical Society
|February 12, 2014
PubMed
まとめ

研究者らは,ブルーボックスサイクロファンを用いて電気化学的に二酸化可能なデイジーチェーンロタキサンを合成した. これらの分子スイッチは,電気化学的なスイッチングで重要な次元変化を示し,ユニークな機械的反応を提供します.

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