水素で満たされたクォーツのような水氷
Timothy A Strobel1, Maddury Somayazulu1, Stanislav V Sinogeikin2
1Geophysical Laboratory, Carnegie Institution of Washington , Washington, D.C. 20015, United States.
Journal of the American Chemical Society
|August 20, 2016
まとめ
研究者は,水素 (H2) +水 (H2O) システムにおける六角形"C0"相構造を解明した. クォーツに似たこのキラル構造は,ゼオライトのようなチャネルの中に重要な水素を宿している. これは,氷の惑星体に関連している.
科学分野:
- 高圧物理学と化学
- 材料科学
- 惑星科学
背景:
- H2 + H2Oシステムは 惑星の内部を理解するために不可欠です
- C0という新しい相が最近発見されましたが,その構造は未解決のままでした.
研究 の 目的:
- C0相の結晶構造を決定する.
- この段階の水素貯蔵メカニズムを理解する.
- 氷の惑星への関連性を評価する
主な方法:
- 局所ラマン光譜法
- シングルクリスタルX線 difraktion
- 粉末X線微分
主要な成果:
- C0相は,名目成分 (H2O) 2H2で,約400MPaと280Kで形成される.
- 水と無秩序なH2分子の渦巻き鎖が互いに貫通しているキラル六角構造を有する.
- 構造はゼオライトのようなチャネルで,重量の5.3%の水素を収納することができる.
結論:
- C0相は,水素結合の格子であり,水素貯蔵の潜在的応用がある.
- その構造的特徴と形成条件は,氷の惑星体の熱力学的環境と関連しています.
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