調節可能な電気伝導性のための3次元テトラチアフルバレンベースの共性有機フレームワーク
Hui Li1, Jianhong Chang1, Shanshan Li1
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University , Changchun 130012 , People's Republic of China.
Journal of the American Chemical Society
|August 11, 2019
まとめ
研究者らは,新しい3Dテトラチアフルワレンベースの共性有機フレームワーク (3D-TTF-COF) を開発した. これらの電気活性材料は 調節可能な伝導性を示し,先進的な分子電子と エネルギー貯蔵アプリケーションの道を切り開きます.
科学分野:
- 材料科学
- 有機化学
- ナノテクノロジー
背景:
- 3D共性有機フレームワーク (COF) の機能化は,そのアプリケーションの拡大に不可欠です.
- 3D COFに電気活性有機基を組み込むことは依然として大きな課題です.
研究 の 目的:
- 3DテトラチアフルバレンベースのCOF (3D-TTF-COF) の最初の合成を報告する.
- 電気化学的活動と電気伝導性を調べるため
主な方法:
- 3D-TTF-COFの合成,非または2倍相互浸透したptsトポロジー.
- 結晶性,多孔性,表面積の特徴づけ
- ヨウ素ドーピングによる酸化還元活性と電気伝導性の評価
主要な成果:
- 3D-TTF-COFの高結晶度,永続的な多孔性,高表面積 (3000m2/gまで) を達成した.
- 調整可能な電気化学的活動と 放射性反応を証明した
- ヨウ素ドーピングで120°Cで最大1.4 × 10−2 S cm−1の電導性を得られた.
結論:
- 新しい3D電動COF材料の設計と合成に成功しました.
- これらの3D-TTF-COFは,分子電子とエネルギー貯蔵における応用が有望であることを示しています.
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