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Updated: Dec 20, 2025

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

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ニッケル-ディピリン複合体を用いた効率的なC-Hアミネーション触媒

Yuyang Dong1, Ryan M Clarke1, Gerard J Porter1

  • 1Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.

Journal of the American Chemical Society
|May 29, 2020
PubMed
まとめ

新しいニッケル触媒は,室温でアリファティックアジドの効率的なC-Hアミネーションを可能にします. この反応は,速度を決定する水素原子抽象段階を経て,広範囲の基質範囲と機能群の許容性を有するN-ヘテロサイクルを形成します.

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