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相关概念视频

Halogens03:01

Halogens

Group 17 elements, known as halogens, are nonmetals. At room temperature, fluorine and chlorine are gases, bromine is a liquid, and iodine a solid. Astatine is a highly unstable radioactive element, so currently, most of its properties are unknown due to its short half-life. Tennessine is a synthetic element also predicted to be in this group.
Properties of Transition Metals02:58

Properties of Transition Metals

Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
Extraction: Advanced Methods00:56

Extraction: Advanced Methods

Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is formed in...

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相关实验视频

Updated: Jul 16, 2026

Preparation of Hydrophobic Metal-Organic Frameworks via Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes for the Removal of Ammonia
12:05

Preparation of Hydrophobic Metal-Organic Frameworks via Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes for the Removal of Ammonia

Published on: October 10, 2013

早期过渡金属 perfluoroalkyl 复合物的早期过渡金属.

Felicia L Taw1, Brian L Scott, Jaqueline L Kiplinger

  • 1Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.

Journal of the American Chemical Society
|December 4, 2003
PubMed
概括

研究人员首次合成和表征了新的 perfluoroalkyl 复合物. 这些具有强大的三甲基键的稳定化合物是使用一种新的三甲基转移试剂制成的.

科学领域:

  • 有机金属化学 有机金属化学
  • 化学 的化学
  • 材料科学 材料科学 材料科学

背景情况:

  • 早期的过渡金属 perfluoroalkyl 复合物很难合成和表征.
  • 了解 perfluoroalkyl 复合物的金属碳键的稳定性和反应性,对于开发新材料和催化剂至关重要.

研究的目的:

  • 为了隔离和结构性地描述难以捉摸的早期过渡金属 perfluoroalkyl 复合物.
  • 为了研究三甲基 (Ti-CF3) 连接的稳定性.
  • 探索三甲基trimethylsilane作为三甲基转移试剂的实用性.

主要方法:

  • (IV) 化物复合物Cp2TiF2与三甲基三甲基 (CF3SiMe3) 的反应.
  • 随后与三甲基三甲酸盐 (Me3SiOTf) 发生反应.
  • 使用光谱方法和单晶X射线分析进行了表征.

主要成果:

  • 成功合成和分离了新型(IV) 三甲基化物 (Cp2Ti ((CF3) ((F)) 和 ((IV) 三甲基三酸盐 (Cp2Ti ((CF3) ((OTf)) 复合物.
  • 结构特征证实了这些独特化合物的形成.
  • 发现-三甲基连接非常强大,没有观察到α-化物相互作用.

更多相关视频

Identifying Per- and Polyfluorinated Chemical Species with a Combined Targeted and Non-Targeted-Screening High-Resolution Mass Spectrometry Workflow
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Identifying Per- and Polyfluorinated Chemical Species with a Combined Targeted and Non-Targeted-Screening High-Resolution Mass Spectrometry Workflow

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Investigating Long-Distance Transport of Perfluoroalkyl Acids in Wheat via a Split-Root Exposure Technique
07:06

Investigating Long-Distance Transport of Perfluoroalkyl Acids in Wheat via a Split-Root Exposure Technique

Published on: September 28, 2022

相关实验视频

Last Updated: Jul 16, 2026

Preparation of Hydrophobic Metal-Organic Frameworks via Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes for the Removal of Ammonia
12:05

Preparation of Hydrophobic Metal-Organic Frameworks via Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes for the Removal of Ammonia

Published on: October 10, 2013

Identifying Per- and Polyfluorinated Chemical Species with a Combined Targeted and Non-Targeted-Screening High-Resolution Mass Spectrometry Workflow
09:04

Identifying Per- and Polyfluorinated Chemical Species with a Combined Targeted and Non-Targeted-Screening High-Resolution Mass Spectrometry Workflow

Published on: April 18, 2019

Investigating Long-Distance Transport of Perfluoroalkyl Acids in Wheat via a Split-Root Exposure Technique
07:06

Investigating Long-Distance Transport of Perfluoroalkyl Acids in Wheat via a Split-Root Exposure Technique

Published on: September 28, 2022

结论:

  • 三甲基三甲基是一种有效的试剂,用于在早期过渡金属上引入三甲基.
  • 合成的 perfluoroalkyl 复合物代表了有机金属化学的重大进步.
  • 强大的Ti-CF3键表明了在催化和材料科学中的潜在应用.