石墨和石墨烯的溶液特性
Sandip Niyogi1, Elena Bekyarova, Mikhail E Itkis
1Department of Chemistry, Center for Nanoscale Science and Engineering, University of California, Riverside, California 92521-0403, USA.
Journal of the American Chemical Society
|June 15, 2006
概括
氧化石墨在与八基亚胺衍生后,在有机溶剂中变得可溶. 这一突破使得研究单层和少层石墨烯板的溶液特性成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 化学 化学 化学
背景情况:
- 石墨是一种分层材料,通常在常见溶剂中不溶.
- 功能化是将可溶性和可加工性赋予碳材料的一个关键策略.
研究的目的:
- 开发一种用于溶解氧化石墨的方法.
- 为了描述由此产生的可溶石墨烯物种.
- 为了研究石墨的溶液特性.
主要方法:
- 氧化石墨中的酸性功能组的共价导化,使用八基胺.
- 在常见的有机溶剂中溶解.
- 原子力显微镜 (AFM) 用于可溶性物种的表征.
主要成果:
- 成功的共价衍生使氧化石墨在有机溶剂中溶解.
- AFM的表征证实了溶液中单层和几层石墨烯板的存在.
- 这项研究报告了对石墨的溶液性质的首次观察.
结论:
- 八甲基亚胺衍生物化是一种有效的方法来实现氧化石墨的溶解性.
- 可溶性物种主要是个体和少层石墨烯板.
- 这项工作为在基于解决方案的应用中探索石墨和石墨烯开辟了新的途径.
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