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相关概念视频

Paramagnetism01:30

Paramagnetism

Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
Ferromagnetism01:31

Ferromagnetism

Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
Magnetic Susceptibility and Permeability01:31

Magnetic Susceptibility and Permeability

In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
Diamagnetism01:26

Diamagnetism

Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets.
Colors and Magnetism03:02

Colors and Magnetism

Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Types of Reversible Electrodes01:24

Types of Reversible Electrodes

For electrode reversibility to be maintained, all the reactants and products involved in the half-reaction must be present at the electrode. There are several types of reversible electrodes (half-cells).In metal-metal-ion electrodes, a metal balances electrochemically with a solution of its own ions. Examples are Cu2+|Cu and Zn2+|Zn. Metals that react with the solvent, like group 1 and most group 2 metals, which react with water, and zinc, which reacts with aqueous acidic solutions, cannot be...

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相关实验视频

Updated: May 10, 2026

Paramagnetic Relaxation Enhancement for Detecting and Characterizing Self-Associations of Intrinsically Disordered Proteins
07:24

Paramagnetic Relaxation Enhancement for Detecting and Characterizing Self-Associations of Intrinsically Disordered Proteins

Published on: September 23, 2021

在水中的一种非向可逆的偏磁开关.

Alexander T Buck1, Joseph T Paletta, Shalika A Khindurangala

  • 1Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA.

Journal of the American Chemical Society
|July 9, 2013
PubMed
概括

研究人员开发了一种使用 bis ((viologen) diradical 的有机偏磁开关. 这种分子通过使用黄[7]uril可逆地改变水中的磁性状态,从而使新的电子和传感应用成为可能.

科学领域:

  • 超分子化学 超分子化学
  • 材料科学 材料科学 材料科学
  • 有机电子 有机电子

背景情况:

  • 可切换磁性材料的开发对于先进技术至关重要.
  • 基于viologen的根基系统为磁性属性控制提供了潜力.
  • 客宿主化学提供了一个分子切换的平台.

研究的目的:

  • 为了设计和表征一种新的有机偏磁开关.
  • 用非共价相互作用来证明可逆磁态循环.
  • 探索可切换磁分子的潜在应用.

主要方法:

  • 合成一个链接 bis ((viologen) dication 的基.
  • 调查与黄[7]uril (CB[7]) 的客宿主复杂化.
  • 在水溶液中的磁性特性表征.
  • 极端相互作用的计算建模.

主要成果:

  • 合成了一种二氧化 () 基,并被证明可以作为一个有机-磁性开关.
  • 在水中通过CB[7]复合实现了二磁性和二磁性状态之间的可逆切换.
  • 计算分析表明,在viologen激素单位之间存在pi-dimer (pimer) 相互作用.

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Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
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Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy

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Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation
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Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation

Published on: August 28, 2017

相关实验视频

Last Updated: May 10, 2026

Paramagnetic Relaxation Enhancement for Detecting and Characterizing Self-Associations of Intrinsically Disordered Proteins
07:24

Paramagnetic Relaxation Enhancement for Detecting and Characterizing Self-Associations of Intrinsically Disordered Proteins

Published on: September 23, 2021

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
10:28

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy

Published on: May 27, 2018

Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation
08:27

Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation

Published on: August 28, 2017

结论:

  • 这项研究提出了一种新的分子开关,在水中具有可调节的磁性.
  • 这些发现为旋转电子,数据存储和化学传感开辟了道路.
  • 开发的系统作为先进的磁性材料和探针的基石.