用氧活性非合聚合物进行电荷传输的扩散合作模型
Kan Sato1, Rieka Ichinoi1, Ryusuke Mizukami1
1Department of Applied Chemistry, Waseda University , Tokyo 169-8555, Japan.
Journal of the American Chemical Society
|December 26, 2017
概括
在聚合物中,由于电荷的移动有限,电荷传输速度很慢. 一个新的超分子系统设计克服了这一点,实现了先进材料的高电荷传递率.
科学领域:
- 电化学
- 聚合物科学
- 材料化学
背景情况:
- 不结合的氧化还原活性聚合物中的电荷传输对于储能应用至关重要.
- 之前的研究指出费用转移速度缓慢,但缺乏定量解释.
- 聚合物链内的氧化还原中心的有限移动性是可疑但未被证明的原因.
研究的目的:
- 在氧化还原活性聚合物中量化解释减少的电荷转移速率常数.
- 提出一种新的设计,以加强这些系统的充电运输.
- 实现与自由溶液系统相比较的高电荷传输速率常数和位点密度.
主要方法:
- 使用扩散合作模型分析电荷传输机制.
- 研究了聚合物结合的氧化还原中心受限布朗运动的影响.
- 提出并从理论上评估了一种氧化还原活性超分子系统.
主要成果:
- 由于有限的布朗运动,双分子和异质电荷转移速率常数减少了10^3-4^倍.
- 确定了氧化还原中心的移动性受限作为缓慢电荷转移的长期不明原因.
- 设计了一种具有高物理流动性的超分子系统,用于氧化还原中心.
结论:
- 不结合的聚合物中氧化还原中心的有限物理移动性显著阻碍了电荷转移.
- 一个新的氧化还原活性超分子系统设计可以克服这些限制.
- 这种方法使得高位密度的电荷传输速率常数超过10^7 M^-1 s^-1,为下一代电化学设备铺平了道路.
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