在单个AIEgen系统中多个可控制的光开关
Peifa Wei1,2, Jing-Xuan Zhang2, Zheng Zhao1,2
1HKUST-Shenzhen Research Institute , No. 9 Yuexing first RD, South Area, Hi-tech Park, Nanshan, Shenzhen 518057, China.
Journal of the American Chemical Society
|January 16, 2018
概括
研究人员开发了一种新的乙烯分子,表现出聚合诱导的排放. 这种智能材料具有可控制的光开关功能, 可实现高级应用.
科学领域:
- 材料科学
- 有机化学
- 摄影化学
背景情况:
- 开发具有多种功能的可光切换材料是一项挑战.
- 现有的系统通常具有单一的功能,在聚合状态下是无排放的,限制了应用.
研究的目的:
- 以聚合诱导排放 (AIE) 合成基于乙烯的分子.
- 在各种条件下研究其多种可控的光响应行为.
主要方法:
- 一个定制的乙烯衍生物的合成.
- 包括Z/E异体化,光循环化和光二体化在内的光响应性行为的表征.
- 对光反应机制的实验和理论分析.
主要成果:
- 合成的分子表现出高效,多重和可控制的光响应行为.
- 已证明可逆Z/E异体化,紫外线诱导的光环化与光增强,以及区域/立体选择性光体化.
- 具有高信号与背景比率的光二维光图.
结论:
- 开发的乙烯分子具有多功能光响应性.
- 这项工作为构建智能多色材料提供了有效的策略.
- 在先进的光学设备和响应材料中的潜在应用.
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