具有srs拓的3D阴性酸共价有机框架
Oussama Yahiaoui1, Andrew N Fitch2, Frank Hoffmann3
1Department of Chemistry , Technische Universität Berlin , BA2, Hardenbergstraße 40 , 10623 Berlin , Germany.
Journal of the American Chemical Society
|April 5, 2018
概括
研究人员使用高协调节合成了一种新的3D阴离子共价有机框架 (COF). 这种新材料SiCOF-5采用了独特的srsnet拓,扩大了先进的多孔材料的可能性.
科学领域:
- 材料化学
- 超分子化学
- 纳米技术
背景情况:
- 合成具有新型拓的3D共价有机框架 (COF) 是很困难的.
- 现有的3D COF仅限于四面体构建块.
研究的目的:
- 用三坐标的srs网来证明一个3D COF的目标合成.
- 扩大COF结构的几何多样性.
主要方法:
- 使用基于高协调节的离子COF的新连接.
- 具有三烯构成块的网状二六坐标[SiO6]2-节点.
- 通过逐步生成源来控制核化和生长速度.
主要成果:
- 已经成功合成了SiCOF-5,一种3D离子COF.
- SiCOF-5结晶在一个双重互透的srs-c网中.
- 框架的组成是Na2[Si(C18H6O6].
结论:
- 实现了具有srs网络拓的新奇3D离子COF的目标合成.
- 在COF结构中证明了超协调节点的实用性.
- 突出了受控反应动力学对成功结晶的重要性.
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