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相关概念视频

Catalysis02:50

Catalysis

30.1K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Hydrogen Bonds00:26

Hydrogen Bonds

131.4K
Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
131.4K
Electric Field01:16

Electric Field

12.3K
Consider two point charges, each exerting Coulomb force on the other. It is possible to describe the Coulomb interaction via an intermediate step by defining a new physical quantity called the electric field.
In the new picture, imagine that the first charge sets up an electric field independent of all other charges in the universe. When another charge comes in its vicinity, the second charge experiences an electric force depending on the electric field at that point. The source charge does not...
12.3K
Determining Electric Field From Electric Potential01:12

Determining Electric Field From Electric Potential

4.9K
The electric field and electric potential are related to each other. If the electric field at various points in the region of interest is known, it can be used to calculate the electric potential difference between any two points. Similarly, if the electric potential is known for various points, then it is possible to calculate the electric field.
In general, regardless of whether the electric field is uniform, it points in the direction of decreasing potential because the force on a positive...
4.9K
Finding Electric Potential From Electric Field01:13

Finding Electric Potential From Electric Field

5.4K
For a system of charges, it is easy to calculate the system's potential because potential is a scalar quantity. However, in some instances where calculating the electric field is more straightforward than finding the potential, the electric field is used to calculate the system's potential. For a positive charge, the electric field is radially outward, and the potential is positive at any finite distance from the positive charge. In such an electric field, the motion away from the...
5.4K
Electric Field Inside a Conductor01:20

Electric Field Inside a Conductor

7.2K
When a conductor is placed in an external electric field, the free charges in the conductor redistribute and very quickly reach electrostatic equilibrium. The resulting charge distribution and its electric field have many interesting properties, which can be investigated with the help of Gauss's law.
Suppose a piece of metal is placed near a positive charge. The free electrons in the metal are attracted to the external positive charge and migrate freely toward that region. This region then...
7.2K

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相关实验视频

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Quantification of Hydrogen Concentrations in Surface and Interface Layers and Bulk Materials through Depth Profiling with Nuclear Reaction Analysis
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Quantification of Hydrogen Concentrations in Surface and Interface Layers and Bulk Materials through Depth Profiling with Nuclear Reaction Analysis

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在催化过程中跟踪Pt/H2接口的电场

Jaeyune Ryu1, Yogesh Surendranath1

  • 1Department of Chemistry , Massachusetts Institute of Technology , Cambridge , Massachusetts 02139 , United States.

Journal of the American Chemical Society
|August 22, 2019
PubMed
概括
此摘要是机器生成的。

在性条件下,由于质子 (H+) 度增加,表面的电场显著放大. 这项研究量化了这种强化场,对于理解催化作用至关重要.

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Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics
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科学领域:

  • 电化学
  • 表面科学
  • 催化剂

背景情况:

  • 了解界面电场对于催化过程至关重要.
  • 在电极表面的质子 (H+) 的行为会影响反应路径.

研究的目的:

  • 在H2/H+催化过程中量化 (Pt) 表面的界面电场大小.
  • 确定表面质子度与电场强度之间的关系.

主要方法:

  • 使用表面催化,pH敏感的非法拉代反应来追踪局部质子 (H+) 度.
  • 在不同的pH和离子强度中保持Pt表面的可逆电极电位.

主要成果:

  • 直接量化了Pt/溶液界面的静电电位下降.
  • 确定接口电场每增加pH单位增加约60mV.

结论:

  • 与酸性条件相比,在性条件下,Pt表面的电场显著放大.
  • 提供对表面催化过程至关重要的电场环境的直接洞察.