碳氧化纤维素纳米晶体的体稳定性窗口:处理,表征和配方方面的考虑.
Julia M Antoniw1, Madeleine T Hallman1, Michael V Kiriakou2
1Department of Chemical and Biological Engineering, University of British Columbia, Vancouver, British Columbia, Canada V6T 1Z4.
Langmuir : the ACS journal of surfaces and colloids
|July 17, 2023
概括
商业生产的碳氧化纤维素纳米晶体 (CNC) 具有定义的合稳定性窗口,对pH,离子强度和度敏感. 超声波可以在这个窗口之外重新分散聚合的CNC.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 合体化学 合体化学
背景情况:
- 纤维素纳米晶 (CNCs) 的生产正在增加,以获得可持续的材料.
- 碳氧化CNC为传统的硫酸CNC提供了替代品.
- 了解CNC的体稳定性对于它们的应用至关重要.
研究的目的:
- 定义碳化CNC (DextraCel) 的合稳定性窗口.
- 在不同的条件下与硫酸CNC相比较稳定性.
- 提供在工业应用中处理CNC的指导方针.
主要方法:
- 根据pH值,离子强度,表面电荷, counterion 和度构建了相位图.
- 确定了碳氧化CNC的pKa.
- 稳定性被评估为有或没有工业相关的添加剂.
主要成果:
- 在不含盐的情况下,碳氧化CNC在pH值3到11 (0.5-1.5重量%) 之间是稳定的.
- 稳定性对离子强度高度敏感,在5mM NaCl.Cl.时聚集.
- 表面电荷和反离子显著影响稳定性;碳氧化CNC在形式更稳定.
结论:
- 碳氧化CNC表现出一种特定的合体稳定性窗口,受溶液条件的影响.
- 稀释或pH调整不能在这个窗口之外恢复稳定性;超声波是有效的再分散.
- 提供了对碳氧化CNC处理的指导方针,以加强其在各种产品中的使用.
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