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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
7.8K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
3.4K
Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation02:47

Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation

18.3K
Introduction
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
18.3K
Preparation of Alkynes: Dehydrohalogenation02:34

Preparation of Alkynes: Dehydrohalogenation

15.9K
Introduction
Alkynes can be prepared by dehydrohalogenation of vicinal or geminal dihalides in the presence of a strong base like sodium amide in liquid ammonia. The reaction proceeds with the loss of two equivalents of hydrogen halide (HX) via two successive E2 elimination reactions.
15.9K
Preparation of Alkynes: Alkylation Reaction02:27

Preparation of Alkynes: Alkylation Reaction

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Introduction
Alkylation of terminal alkynes with primary alkyl halides in the presence of a strong base like sodium amide is one of the common methods for the synthesis of longer carbon-chain alkynes. For example, treatment of 1-propyne with sodium amide followed by reaction with ethyl bromide yields 2-pentyne.
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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保护基的Ag20Rh2纳米集群具有原子精度:结构分析和三功能催化应用.

Lei Wang1, Leyi Chen1, Lubing Qin1

  • 1New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Center, Guangzhou, 510006, China.

Chemistry, an Asian journal
|August 25, 2023
PubMed
概括

原子精确的银-纳米集群 (Ag20Rh2) 显示出优越的催化活性,用于多种反应,包括进化和污染物降解,由于其独特的结构和暴露的活性点.

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在Ag20Rh2纳米集群中.的演化反应反应.甲基色降解的方法减少4-尼托醇的使用.结构分析是一种结构分析.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 纳米技术纳米技术
  • 催化剂是一种催化剂.

背景情况:

  • 原子精确的纳米集群具有独特的催化性能.
  • 银合金 (AgRh) 的纳米集群对催化有兴趣.
  • 了解纳米集群结构-活动关系至关重要.

研究的目的:

  • 为了合成和描述一个原子精确的Ag20Rh2纳米集群.
  • 为了研究Ag20Rh2.2.的三功能催化应用.
  • 将Ag20Rh2的催化性能与较大的AgRh纳米粒子进行比较.

主要方法:

  • 用原子精度合成基尼尔保护的Ag20Rh2纳米集群.
  • 使用先进技术进行结构性表征.
  • 在电化学演化反应 (HER),4-尼托芬醇还原和甲基色降解中的催化活性评估.

主要成果:

  • Ag20Rh2纳米团具有扭曲的棒状结构,具有Ag4@Rh2内核和Ag8立方体.
  • Ag20Rh2 具有四个自由价值电子的超原子特征.
  • 在所有测试反应中,与较大的AgRh纳米粒子相比,Ag20Rh2的催化性能优越.

结论:

  • 这项研究引入了一种新的基尼尔保护的AgRh纳米集群,具有原子精度.
  • Ag20Rh2的超小尺寸和暴露的活性部位有助于其增强的催化效率.
  • 原子精确的纳米集群是多功能催化剂的有希望的候选者.