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相关概念视频

Nomenclature of Aromatic Compounds with Multiple Substituents01:11

Nomenclature of Aromatic Compounds with Multiple Substituents

7.8K
When more than one substituent is present on the benzene ring, the IUPAC nomenclature depends on the number of substituents present.
For disubstituted benzene derivatives, with two groups attached to the benzene ring, three constitutional isomers are possible. For example, consider dimethyl benzene, often called xylene, where the second methyl group can be substituted at the second, third, or fourth carbon. The relative position of the substituents is represented by prefixes ortho, meta, or...
7.8K
Nomenclature of Aromatic Compounds with a Single Substituent01:23

Nomenclature of Aromatic Compounds with a Single Substituent

8.2K
Benzene is the simplest aromatic hydrocarbon or arene. The IUPAC names for simple monosubstituted benzene derivatives are derived by adding the substituent's name as a prefix to the parent benzene. For example, halobenzene, where the halogen could be fluoro (F), chloro (Cl), bromo (Br), and iodo (I).
8.2K
Reactions at the Benzylic Position: Oxidation and Reduction00:59

Reactions at the Benzylic Position: Oxidation and Reduction

3.7K
The benzylic position describes the position of a carbon atom attached directly to a benzene ring. Benzene by itself does not undergo oxidation. In contrast, the benzylic carbon is quite reactive in the presence of strong oxidizing agents such as KMnO4 or H2CrO4. Therefore, alkylbenzenes are readily oxidized to benzoic acid, irrespective of the type of alkyl groups.
3.7K
Organic Compounds03:02

Organic Compounds

51.4K
All living things are formed mostly of carbon compounds called organic compounds. The category of organic compounds includes both natural and synthetic compounds that contain carbon. Although a single, precise definition has yet to be identified by the chemistry community, most agree that a defining trait of organic molecules is the presence of carbon as the principal element, bonded to hydrogen and other carbon atoms. However, some carbon-containing compounds such as carbonates, cyanides, and...
51.4K
Hydroboration-Oxidation of Alkenes03:08

Hydroboration-Oxidation of Alkenes

8.2K
In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
8.2K
ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH301:11

ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH3

6.0K
All ortho–para directors, excluding halogens, are activating groups. These groups donate electrons to the ring, making the ring carbons electron-rich. Consequently, the reactivity of the aromatic ring towards electrophilic substitution increases. For instance, the nitration of anisole is about 10,000 times faster than the nitration of benzene. The electron-donating effect of the methoxy group in anisole activates the ortho and para positions on the ring and stabilizes the corresponding...
6.0K

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相关实验视频

Updated: Jul 1, 2025

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
08:43

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives

Published on: January 19, 2016

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-2-尼尔3-甲基-氧-4--2--氧) 酸.

Cresten Moodley1, Alfred Muller1, Yonas H Belay1

  • 1Synthesis and Catalysis Research Centre, Department of Chemical Sciences, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg, 2006, South Africa.

IUCrData
|March 8, 2024
PubMed
概括

这项研究详细介绍了C14H12O4化合物的晶体结构,揭示了由C-H...O相互作用形成的二维结构. 基团表现出扭曲,而晶体包装形成了一个齐格扎格的图案.

科学领域:

  • 晶体学 晶体学是指结晶学.
  • 有机化学 有机化学
  • 固态化学 固态化学

背景情况:

  • 了解分子相互作用和有机固体的包装对于材料科学至关重要.
  • 标题化合物,C14H12O4,由于其功能组,为结构分析提供了一个有趣的案例.

研究的目的:

  • 阐明标题化合物的晶体结构和分子间相互作用.
  • 分析基组的构成和固态中的包装安排.

主要方法:

  • 使用单晶X射线衍射来确定分子和晶体结构.
  • 进行了分子间C-HO相互作用和二面角的分析.

主要成果:

  • 不对称的单元包含两个独立的C14H12O4分子,通过C-HO键形成二维实体.
  • 观察到基组在基平面外显著扭曲,二面角从7.92 13°到25.42 8°.
  • 晶体包装沿着c轴沿着一个明显的齐格扎格图案.

结论:

  • 该研究成功地描述了标题化合物的晶体结构和超分子组合.
  • 观察到的形状偏好和包装图案为这种有机分子的固态行为提供了洞察力.
关键词:
晶体结构 晶体结构这就是Dimer Dimer的意思.通过联结,形成联结.

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