一瞬间融化无形冰的冰.
Nathan J Mowry1, Constantin R Krüger1, Gabriele Bongiovanni1
1Ecole Polytechnique Fédérale de Lausanne (EPFL), Laboratory of Molecular Nanodynamics, CH-1015 Lausanne, Switzerland.
The Journal of chemical physics
|May 9, 2024
概括
研究人员发现,用激光快速化无形冰会使其结晶,即使在快速加热速度下. 这与实现玻璃化的快速冷却形成鲜明对比,为水提供了新的洞察力.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 生物物理学的生物物理.
背景情况:
- 水可以通过快速冷却来玻璃化 (形成玻璃),避免在深度超冷状态的"无人之地"中结晶.
- 了解水在这种超冷状态下的行为对于包括冷电子显微镜在内的各种科学领域至关重要.
研究的目的:
- 为了研究反向玻璃化过程:使用微秒激光脉冲快速化无形冰.
- 为了阐明极端加热条件下水的结晶机制.
主要方法:
- 使用高功率微秒激光脉冲,对纯水样品 (无形冰) 进行闪融化.
- 时间解析的电子衍射观察激光加热期间和之后的结构变化.
- 无形固态水和超灭玻璃水之间的结晶动力学的比较.
主要成果:
- 尽管加热速度极高 (>5 × 10^6 K/s),但观察到水的暂时结晶.
- 这种结晶发生了即使类似的冷却速率 (10^7 K/s) 可以实现玻璃化.
- 对于不同形式的无形冰,确定了不同的结晶动力学.
结论:
- 这项研究揭示了无形冰在激光诱导的快速融化过程中出乎意料的结晶行为.
- 这些发现挑战了关于水的相变的假设,并提供了关于其在"无人之地"的动态的新数据.
- 这些结果对于推进微秒时间解析的冷电子显微镜技术至关重要.
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