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Updated: Jun 8, 2025

Reverse Microemulsion-mediated Synthesis of Monometallic and Bimetallic Early Transition Metal Carbide and Nitride Nanoparticles
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Reverse Microemulsion-mediated Synthesis of Monometallic and Bimetallic Early Transition Metal Carbide and Nitride Nanoparticles

Published on: November 27, 2015

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化学稳定的IV-V组过渡金属碳化物薄膜在基环境中.

Abdul Rehman1, Robbert W E van de Kruijs1, Wesley T E van den Beld1

  • 1Industrial Focus Group XUV Optics, MESA+ Institute for Nanotechnology, University of Twente, Drienerlolaan 5, Enschede 7522NB, The Netherlands.

The journal of physical chemistry. C, Nanomaterials and interfaces
|November 6, 2024
PubMed
概括

过渡金属碳化物 (TMC) 薄膜在气环境中显示出有前途的保护性涂层. 某些TMC具有稳定的碳化碳碳含量,在高温下抵抗基攻击.

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Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride

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The presence of electron-donating, electron-withdrawing, or conjugating groups adjacent to a radical center, imparts electronic stabilization to the radicals. Examples of such electronically-stabilized radicals are triphenylmethyl, tetramethylpiperidine‐N‐oxide, and 2,2‐diphenyl‐1‐picrylhydrazyl. These radicals are remarkably stable and are known as persistent radicals. Some of the persistent radicals can even be isolated and purified.
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Introduction
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