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相关概念视频

Mortar01:29

Mortar

Mortar, a mixture of Portland cement, hydrated lime, sand, and water, is a crucial binding material in construction. Its primary function is to join masonry units together, filling gaps and ensuring a uniform distribution of weight across the structure. This helps in preventing potential weaknesses. Mortar also serves as a protective barrier against environmental elements such as water and wind, thereby safeguarding the interior of the structure. It also compensates for surface irregularities...
Bonding and Strength of Aggregate01:12

Bonding and Strength of Aggregate

The bond between aggregate particles and the cement matrix is significantly influenced by the shape and surface texture of the aggregates. High-strength concretes benefit from a rougher texture, which leads to stronger bonding due to greater adhesion. Angular aggregates with larger surface areas also enhance this bond. The bonding quality, however, is complex to assess as no universally accepted test exists. Good bonding is indicated when a crushed concrete specimen shows some aggregate...
Accelerators01:17

Accelerators

Accelerators in concrete serve as admixtures to speed up the hardening process, enabling the concrete to achieve early strength faster. Although accelerators do not necessarily impact the time it takes concrete to set, they reduce this time in practice. A common accelerator is calcium chloride, which is particularly useful for hastening early strength development in cold weather or for rapid repair jobs that require quick heat generation after mixing.
The effectiveness of calcium chloride can...
Retarders01:19

Retarders

Retarders are chemical admixtures designed to extend the setting time, which is especially useful when there is a delay in sequential concrete pours to prevent cold joints and to achieve a cohesive structure. Retarders, when used in appropriate amounts, can also enhance the architectural appearance of exposed aggregate finishes.
The function of retarders is to delay the setting of concrete, and this effect can be measured using a penetration test. The retardation process involves adding...
Superplasticizers01:30

Superplasticizers

Superplasticizers are advanced admixtures that enhance the workability of concrete by lowering the water content without compromising the strength of the material. These substances are highly effective water reducers, improving concrete flow, making it easier to work with, and enabling concrete to reach inaccessible areas or densely reinforced sections without mechanical vibration. The key components in superplasticizers are either sulfonated melamine or naphthalene formaldehyde condensates,...
Additives and Fillers in Concrete01:29

Additives and Fillers in Concrete

Additives and fillers are integral to enhancing the properties of concrete. Pozzolans and blast-furnace slag are additives or admixtures due to their reactions with calcium hydroxide released during cement hydration. Fillers, which are finely ground and similar in fineness to Portland cement, improve concrete attributes such as workability density, and reduce capillary bleeding or cracking. Some fillers possess hydraulic properties or participate in benign reactions within the cement paste.
The...

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使用结构指导液体添加剂对地质石胺酸框架进行机械化学固体选

Ivana Brekalo1,2,3, Katarina Lisac1, Joseph R Ramirez2

  • 1Division of Physical Chemistry, Ruđer Bošković Institute, Zagreb 10000, Croatia.

Journal of the American Chemical Society
|July 24, 2025
PubMed
概括

机械化学液体辅助研磨 (LAG) 已成功选出胺酸 (ZnIm2) 形式. 这种方法发现了八种新的拓形式,加速了金属有机框架的发现.

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科学领域:

  • 材料科学
  • 化学学
  • 晶体学

背景情况:

  • 伊米达酸盐 (ZnIm2) 是最简单的焦化伊米达酸盐框架材料.
  • 发现ZnIm2的新形式对于了解金属有机框架至关重要.
  • 现有的合成方法在探索多种MOF结构方面存在局限性.

研究的目的:

  • 系统地使用液体辅助研磨 (LAG) 来选 ZnIm2 形式.
  • 探索不同液体添加剂对ZnIm2合成的影响.
  • 发现ZnIm2的新型拓和晶体学上的不同形式.

主要方法:

  • 使用机械化学液体辅助研磨 (LAG) 对45种液体添加剂进行系统选.
  • 使用分散校正周期密度函数理论 (DFT) 的计算探索.
  • 合成的 ZnIm2 形式的表征,包括晶体分析.

主要成果:

  • 确定了八种不同的ZnIm2拓形式,包括两种新的crb (BCT) 拓形式.
  • 合成了13种不同晶体的固体形式,无形相和中断的moc-Zn4Im8HIm.
  • 地方集团加速了合成并指导了不同拓的MOF的形成.

结论:

  • 激光雷达是一个强大的机械化学工具,用于发现新型金属有机材料.
  • 液体添加剂可以显著影响和指导MOF合成.
  • 这项研究表明了LAG在预测添加剂导向的MOF合成方面的潜力.