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Metal-Ligand Bonds02:51

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
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Ionic Bonding and Electron Transfer02:48

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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The minerals contained in all of the food we consume are essential for our organ systems. However, certain essential minerals, such as calcium, phosphorus, magnesium, manganese, and fluoride, largely affect bone health.
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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
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Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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离子作为功能性材料

Nathan C Frey1, Robert J Gilliard1

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Building 18-596, Cambridge, Massachusetts 02139-4307, United States.

Journal of the American Chemical Society
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概括
此摘要是机器生成的。

研究人员探索了离子,即离子,它们在发光材料中的潜力. 确定了关键的设计原则,以提高它们的稳定性和光学特性,用于先进的应用.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 无机化学 无机化学
  • 有机电子 有机电子

背景情况:

  • 离子 ([LBR2]+) 是反应性易斯酸性离子.
  • 它们的反应性在历史上限制了对它们光电子性质的研究.
  • 需要了解功能性材料的稳定性因素和光学转换.

研究的目的:

  • 对定制循环离子的设计原则进行审查.
  • 专注于它们作为功能发光材料的应用.
  • 突出最近的进展和未来的研究方向.

主要方法:

  • 对离子的设计概念的文献综述.
  • 分析影响稳定性和发光度的因素.
  • 检查在系统中观察到的特定光学现象.

主要成果:

  • 确定了关键的设计原则:联体的身份,环的大小,异构原子的结合和对抗离子的选择.
  • 证明了发射性和刺激反应性离子的隔离和发现.
  • 观察到的现象包括TICT,AIE,激发合和热色.

结论:

  • 循环离子可以设计为可调节的低能LUMO材料.
  • 设计策略可以控制稳定性和光学特征.
  • 这些发现为主要组元素材料化学提供了路线图.