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A New Preparative Method for Allylic Indium(III) Reagents by Reductive Transmetalation of pi-Allylpalladium(II) with
1Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.
Organic Letters
|May 18, 2000
Abstract:
A reductive transmetalation of the pi-allylpalladium(II) complexes, generated in situ from a catalytic amount of a palladium(0) complex and a variety of allylic substrates, with indium(I) salts proceeded smoothly in various solvents, providing a new route for allylindium(III) reagents.