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A new stacking motif: complex alloy structures interpreted as modulated structures.

M Uchida1, Y Matsui

  • 1National Institute for Research in Inorganic Materials, Tsukuba, Ibaraki 305-0044, Japan. uchidam@nirim.go.jp

Acta Crystallographica. Section B, Structural Science
|August 16, 2000
PubMed
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Complex aluminide structures like manganese aluminide (Al4Mn) are reinterpreted as modulated structures. This new perspective reveals insights into atomic vacancies and stacking motifs relevant to quasicrystals.

Area of Science:

  • Materials Science
  • Crystallography
  • Solid State Chemistry

Background:

  • Previous models described complex aluminides (lambda-Al4Mn, kappa-Al177Cr49Ni, epsilon-Al4Cr) as aggregations of clusters.
  • These descriptions lacked a unified structural interpretation for related complex alloy phases.

Purpose of the Study:

  • To re-evaluate and reinterpret the structures of specific manganese, chromium nickel, and chromium aluminides.
  • To establish a new structural framework for understanding complex alloys and quasicrystal-related phases.

Main Methods:

  • Analysis of atomic arrangements in lambda-Al4Mn, kappa-Al177Cr49Ni, and epsilon-Al4Cr.
  • Interpretation of structural components based on close-packed layers and ordered atomic vacancies.

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Main Results:

  • The structures of lambda-Al4Mn, kappa-Al177Cr49Ni, and epsilon-Al4Cr are reclassified as modulated structures.
  • These modulated structures are fundamentally composed of close-packed atomic layers featuring ordered vacancies.
  • The identified atomic stacking motif is prevalent in phases associated with icosahedral and decagonal quasicrystals.

Conclusions:

  • The modulated structure model provides a more accurate description of these complex aluminides.
  • This revised understanding facilitates the study of complex alloys and the broader field of quasicrystal research.
  • The findings offer a new perspective on the relationship between complex alloys and quasicrystalline materials.