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Published on: November 21, 2013
Pressure-induced hydrogen bonding: structure of D2S phase I'
1Department of Physics and Astronomy, The University of Edinburgh, Edinburgh EH9 3JZ, United Kingdom.
Abstract:
The full structure of the high-pressure cubic phase I' of hydrogen sulfide has been solved using neutron diffraction data. The molecules are partially rotationally disordered about the <111> axes, as in phase II at ambient pressure but with markedly greater nonuniformity of the toroidal D distribution. The changes in structure at the II-->I' transition signal the onset of significant pressure-induced hydrogen bonding.
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