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Benzyl 5-carboxy-4-ethyl-3-methylpyrrole-2-carboxylate
M Ramos Silva1, A Matos Beja, J A Paixão
1CEMDRX, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade de Coimbra, P-3000 Coimbra, Portugal.
Acta Crystallographica. Section C, Crystal Structure Communications
|October 12, 2000
Abstract:
In the title compound, C(16)H(17)NO(4), the benzyloxycarbonyl group is anti to the pyrrolic N atom. The molecules are joined into head-to-head dimers by hydrogen bonds involving the carboxylic acid groups. There is orientational disorder of these groups over two positions with approximately equal occupancy. A weaker hydrogen bond between the pyrrolic N atom and the carbonyl O atom of the benzyloxycarbonyl group joins the dimers into chains running parallel to the [110] direction.