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A low-cost non instrumental method for semiquantitative determination of mercury in fish
A V Yallouz1, R Calixto de Campos, S Paciornik
1Department of Analytical Chemistry, Mineral Center of Technology/CNPq, Cidade Universitária, Rio, Brazil.
Abstract:
A non instrumental method for the semiquantitative determination of mercury in fish is described. The sample is acid digested and the mercury vapor released after chemical reduction with SnCl2. The mercury vapor is then collected on a detecting paper covered with an emulsion of Cu2I2, 3% carboxymethylcellulose and MgCl2 as moistener agent. The colored Cu2[HgI4] complex is formed and the color intensity is proportional to the mercury concentration in the original sample. Parameters such as sample mass/digestion solution volume ratio, emulsion composition, paper covering technique, carrier gas flow were investigated. Comparative studies using CVAAS and digital color analysis after scanning the papers confirmed the applicability of the method to real samples.