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Updated: Oct 3, 2026

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
Published on: May 15, 2017
Crossover from first-order to critical wetting: short-range tricritical wetting
D Ross1, D Bonn, A I Posazhennikova
1National Institute of Standards & Technology, 100 Bureau Drive, Stop 8360, Gaithersburg, Maryland 20899-8360, USA. david.ross@nist.gov
Abstract:
We study wetting in liquid mixtures of methanol and the n-alkanes. Mixing alkanes of different chain lengths, we can examine the crossover between critical (continuous) and first-order (discontinuous) wetting transitions. Measurements of the film thickness and surface specific heat exponent indicate that for carbon number n between 11 (undecane) and 9 (nonane), there is a crossover from first-order to critical wetting with a tricritical wetting point between an effective alkane carbon number of 9.6 and 10. The observed variation of the specific heat exponent in the tricritical region agrees fairly well with the predictions of a simple mean-field model with only short-range interactions.
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