Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Three-coordinate copper(II)-phenolate complexes.

B A Jazdzewski1, P L Holland, M Pink

  • 1Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, USA.

Inorganic Chemistry
|November 13, 2001
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Implementation of Positive Advanced Recovery Connections in Primary and Secondary Mental Health Care-A Registered Advanced Nurse Practitioner-Led Initiative.

Journal of advanced nursing·2024
Same author

[Use of the anatomical cemented femoral stem SAS I: mid-term results].

Acta chirurgiae orthopaedicae et traumatologiae Cechoslovaca·2015
Same author

Is the Bis(μ-oxo)dicopper Core Capable of Hydroxylating an Arene?

Angewandte Chemie (International ed. in English)·2014
Same author

A Diazoalkane Derivative of a Polyoxometalate: Preparation and Structure of [Mo6 O18 (NNC(C6 H4 OCH3 )CH3 )](2-).

Angewandte Chemie (International ed. in English)·2014
Same author

An electromyographic analysis of the upper extremity in pitching.

Journal of shoulder and elbow surgery·2012
Same author

Anterior capsulolabral reconstruction of the shoulder in athletes.

Journal of shoulder and elbow surgery·2012
Same journal

Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo<sub>2</sub>O<sub>5</sub>(IO<sub>3</sub>)<sub>4</sub>]<sup>2-</sup> for Nonlinear Optical Crystal Design.

Inorganic chemistry·2026
Same journal

Synthesis and Reactivity of Boron Triflate and Bistriflimide Complexes Bearing Two <i>ortho</i>-Carboranes.

Inorganic chemistry·2026
Same journal

Switchable Fluorescence of a Three-Dimensional Coordination Polymer Based on Reversible Single-Crystal to Single-Crystal Photoreaction.

Inorganic chemistry·2026
Same journal

8-Aminoquinoline Pendant Ligand-Driven Proton Shuttling in Copper Electrocatalysis for Enhanced Proton Reduction into Hydrogen Gas.

Inorganic chemistry·2026
Same journal

Observation of Structural and Electronic Transitions in Bimetallic Chalcogenide of Copper Tantalum Trisulfide via Pressure Engineering.

Inorganic chemistry·2026
Same journal

Theoretical Structure Prediction and High-Pressure Synthesis of a Layered Sodium Silicide Zintl Phase: Na<sub>2</sub>Si<sub>3</sub>.

Inorganic chemistry·2026
See all related articles

Novel three-coordinate copper(II)-phenolates were synthesized and characterized. These complexes exhibit unique structural dynamics and reactivity with dioxygen, offering insights into copper coordination chemistry.

Area of Science:

  • Coordination Chemistry
  • Organometallic Chemistry
  • Materials Science

Background:

  • Exploration of copper complexes with beta-diketiminate ligands and phenolate groups.
  • Understanding the electronic and structural properties of low-coordinate copper species.

Purpose of the Study:

  • To synthesize and characterize novel three-coordinate copper(II)-phenolates.
  • To investigate the structural dynamics and electronic properties of these complexes.
  • To explore their reactivity, particularly with dioxygen.

Main Methods:

  • Synthesis of copper(II)-phenolates using thallium phenolates and beta-diketiminate ligands.
  • Characterization by X-ray crystallography, UV-vis, EPR, and Resonance Raman spectroscopy.
  • Electrochemical studies using cyclic voltammetry.

Related Experiment Videos

Main Results:

  • Isolation of novel three-coordinate Cu(II)-phenolates, LCuOAr.
  • Structural analysis revealed short Cu-O distances and irregular N-Cu-O angles, with one complex showing a reversible phase transition.
  • Spectroscopic and electrochemical data indicated phenolate to Cu(II) ligand-to-metal charge transfer and stabilized Cu(II) states.

Conclusions:

  • The synthesized copper(II)-phenolates possess unique structural and electronic features.
  • The complexes display unusual reactivity towards dioxygen.
  • The study provides valuable data on low-coordinate copper chemistry and its potential applications.