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Running rings around RNA: a superfamily of phosphate-dependent RNases

Martyn F Symmons1, Mark G Williams, Ben F Luisi

  • 1Dept of Biochemistry, University of Cambridge, Cambridge, UK.

Insights

The structure of polynucleotide phosphorylase (PNPase) reveals insights into RNA degradation. This study supports PNPase

Area of Science:

  • Molecular Biology
  • Structural Biology
  • Biochemistry

Background:

  • Exosomes and degradosomes are multienzyme complexes responsible for messenger RNA (mRNA) degradation.
  • These complexes contain phosphate-dependent exoribonucleases, such as Ribonuclease PH (RNase PH), which degrade RNA from the 3'-end.

Purpose of the Study:

  • To elucidate the atomic structure of polynucleotide phosphorylase (PNPase) from Streptomyces antibioticus, a member of the RNase PH superfamily.
  • To use structural information to understand the evolutionary origins and oligomeric assembly of RNase PH-like enzymes.

Main Methods:

  • X-ray crystallography was employed to determine the atomic structure of PNPase.

Main Results:

  • The study provides the first atomic structure of an RNase PH superfamily member.
  • The trimeric structure of PNPase, composed of multidomain subunits, suggests evolution through gene duplication of an RNase PH-like enzyme.
  • The structure offers potential explanations for the formation of ring-like oligomers involved in processive RNA degradation.

Conclusions:

  • The determined structure of PNPase provides crucial insights into the RNase PH superfamily.
  • Structural data supports an evolutionary model of gene duplication for PNPase.
  • The findings may explain the mechanism of processive RNA degradation by RNase PH-like enzyme oligomers.

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