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CsMoO2(HO3P-CH2-PO3): a new metallodiphosphonate with a hybrid framework
Karin Barthelet1, Didier Riou, Gerard Férey
1Institut Lavoisier, UMR CNRS C 8637, Université de Versailles, Saint-Quentin-en-Yvelines, 45 Avenue des Etats Unis, 78035 Versailles Cedex, France.
Abstract:
Crystals of caesium molybdenomethylenediphosphonate, [CsMoO(2)(CH(3)O(6)P(2))], were hydrothermally synthesized at 473 K. The monoclinic structure, as determined from single-crystal X-ray diffraction, is two-dimensional and consists of stacked mixed layers of corner-sharing tetrahedral diphosphonate groups and MoO(6) octahedra, between which Cs+ cations are intercalated.