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Updated: Sep 30, 2026

Determination of the Photoisomerization Quantum Yield of a Hydrazone Photoswitch
Published on: February 7, 2022
Photoinduced quantum interference antiresonances in pi-conjugated polymers
R Osterbacka1, X M Jiang, C P An
1Department of Physics, Abo Akademi University, Porthansgatan 3, FIN-20500 Turku, Finland.
Abstract:
We observed photoinduced quantum interference antiresonances between several discrete infrared-active vibrations and the lower-polaron continuous absorption band in a series of pi-conjugated polymer films having superior planar orders, where the polaron transition energy is relatively small. The photoinduced Fano-type antiresonances are well explained by extending the amplitude mode model beyond the adiabatic limit. The agreement between the data and the model confirms the presence of a continuous electronic band above the polaron state. We show that high frequency modes are strongly coupled to electrons, with implications for superconductivity.
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