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Related Experiment Videos

Dabconium orthofluoroberyllate hemihydrate.

Lee A Gerrard1, Mark T Weller

  • 1Department of Chemistry, University of Southampton, Southampton, Hampshire SO17 1BJ, England. lag4@soton.ac.uk

Acta Crystallographica. Section C, Crystal Structure Communications
|July 3, 2002
PubMed
Summary

This study reveals the crystal structure of 1,4-diazoniabicyclo[2.2.2]octane tetrafluoroberyllium hemihydrate. It forms a 3D network through hydrogen bonding between inorganic and organic units and water molecules.

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Area of Science:

  • Crystal engineering
  • Inorganic chemistry
  • Supramolecular chemistry

Background:

  • Hydrogen bonding plays a crucial role in the self-assembly of crystal structures.
  • Understanding the interplay between organic cations and inorganic anions is key to designing novel materials.

Purpose of the Study:

  • To elucidate the crystal structure of 1,4-diazoniabicyclo[2.2.2]octane tetrafluoroberyllium hemihydrate.
  • To investigate the role of hydrogen bonding in forming the extended network.

Main Methods:

  • Single-crystal X-ray diffraction was used to determine the crystal structure.
  • Analysis of hydrogen bonding interactions was performed.

Main Results:

  • The structure exhibits alternating organic (C(6)H(14)N(2)(2+)) and inorganic ([BeF(4)](2-)) units in the ac plane, forming double chains.

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  • These chains assemble into a 2D sheet via hydrogen bonds to water molecules.
  • Weak hydrogen bonds link the sheets into a 3D network along the b axis.

    • Conclusions:

    • The crystal structure is a 3D network formed by organic cations, inorganic anions, and water molecules.
    • Hydrogen bonding is the primary driving force for the observed network architecture.
    • This study provides insights into the formation of layered structures with potential applications in materials science.