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Highly saddle shaped (porphyrinato)iron(III) iodide with a pure intermediate spin state
Mikio Nakamura1, Takahisa Ikeue, Yoshiki Ohgo
1Department of Chemistry, Toho University School of Medicine, Ota-ku, Tokyo 143-8540, Japan. mnakamu@med.toho-u.ac.jp
Chemical Communications (Cambridge, England)
|July 12, 2002
Abstract:
Combined analyses using NMR, EPR and Mössbauer spectroscopy as well as SQUID magnetometry have revealed that highly saddle shaped Fe(OETPP)I adopts an essentially pure intermediate spin state in spite of the coordination of an iodide ligand.