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Ni(II) N4-macrocycle grafted crown ether: caesium cobalt(III) bis(dicarbollide) coordination polymer
Nino Malic1, Peter J Nichols, Colin L Raston
1School of Chemistry, Monash University, Clayton 3800, Melbourne, Australia.
Abstract:
A mixture of a Ni(TMTAA) grafted crown ether and Cs[Co(C2B9H11)2] in toluene-CH2Cl2 affords a 1:1 complex, comprised of layers of infinite two-dimensional polymeric arrays separated by layers of the cobalticarborane anion which themselves form two B-H...Cs+ hydrogen interactions.