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1D silver(I) complex of nitronyl nitroxide with strong spin-spin interaction through silver(I) ion
Deqing Zhang1, Liang Ding, Wei Xu
1Organic Solids Laboratory, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China. dqzhang@infoc3.icas.ac.cn
Chemical Communications (Cambridge, England)
|July 18, 2002
Abstract:
A 1D silver(I) complex of nitronyl nitroxide was prepared and its structure was determined by X-ray diffraction analysis; magnetic studies indicate that the spin-spin interaction of nitronyl nitroxides through silver(I) ions along the chain are fairly strong (J/kb = -84 K).