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Transcyclometalation, a versatile methodology for multiple metal-carbon bond formation with multisite ligands
Harm P Dijkstra1, Martin Albrecht, Gerard van Koten
1Debye Institute, Department of Metal-Mediated Synthesis, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands.
Chemical Communications (Cambridge, England)
|July 18, 2002
Abstract:
Transcyclometalation has been successfully applied for the multi-platination and -ruthenation of 'chartwheel'-type ligand systems containing six potential metal binding sites, thus providing a method for multiple metal-carbon bond formation via C-H bond activation which is superior to established cyclometalation protocols.