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Amplification of a cyclic mixed-metalloporphyrin tetramer from a dynamic combinatorial library through orthogonal
Eugen Stulz1, Yiu-Fai Ng, Sonya M Scott
1University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW.
Chemical Communications (Cambridge, England)
|July 18, 2002
Abstract:
A cyclic porphyrin tetramer, consisting of two bis-phosphine substituted zinc(II) porphyrin units and two Rh(III)TPP units, is selected and amplified virtually quantitatively from a dynamic combinatorial library using 4,4'-bipy as a scaffold and using orthogonal binding modes.