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Updated: Sep 29, 2026

Green Synthesis of Quinoline-Based Ionic Liquid
Published on: September 27, 2024
Solvation of 1-butyl-3-methylimidazolium hexafluorophosphate in aqueous ethanol--a green solution for dissolving
R P Swatloski1, A E Visser, W M Reichert
1Department of Chemistry, Center for Green Manufacturing, University of Alabama, Tuscaloosa, AL 35487, USA.
Abstract:
The relatively hydrophobic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate has been found to be totally miscible with aqueous ethanol between 0.5 and 0.9 mol fraction ethanol, whereas the ionic liquid is only partially miscible with either pure water or absolute ethanol; the ability to dissolve 1-butyl-3-methylimidazolium hexafluorophosphate in a 'green' aqueous solvent system has important implications for cleaning, purification, and separations using ionic liquids.
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