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Synthesis of the first 2,3-dihydro-1,2,3-azadiphosphete complex
E Ionescu1, P G Jones, R Streubel
1Institut für Anorganische und Analytische Chemie der Technischen Universität Braunschweig, Postfach 3329, D-38023 Braunschweig, Germany.
Chemical Communications (Cambridge, England)
|October 26, 2002
Abstract:
Synthesis of the first 2,3-dihydro-1,2,3-azadiphosphete complex was achieved via thermal reaction of a 2H-azaphosphirene complex in o-xylene, whereby a 2,5-dihydro-1,3-diaza-2,5-diphosphinine complex and a further unidentified byproduct were formed; the structure of the title compound was established through an X-ray single-crystal diffraction study.