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Spontaneous resolution and absolute configuration of a coordination polymer formed by MnII and a ferrocene-based
Christian Sporer1, Klaus Wurst, David B Amabilino
1Institut für Allgemeine Anorganische und Theoretische Chemie, Universität Innsbruck, A-6020 Innrain 52a, Austria.
Chemical Communications (Cambridge, England)
|November 15, 2002
Abstract:
Crystallisation of a ferrocenyl bis(nitronyl nitroxide) with manganese(II) bis(hexafluoroacetylacetonate) gives rise to spontaneous resolution of a coordination polymer formed by the two units creating seven sources of chirality.