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A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO-containing poly(alkoxyamine ester)s
Hideyuki Otsuka1, Koichiro Aotani, Yuji Higaki
1Institute for Fundamental Research of Organic Chemistry, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-858, Japan. otsuka@ms.ifoc.kyushu-u.ac.jp
Chemical Communications (Cambridge, England)
|December 14, 2002
Abstract:
A dynamic covalent polymer incorporating thermally alkoxyamine units in the main chain was synthesized. Due to a radical crossover reaction between the alkoxyamine units, an interchange of the main chains in poly(alkoxyamine ester) was observed on heating.