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Novel nucleophilic trifluoromethylation of vicinal diol cyclic sulfates
Naoto Takechi1, Samia Ait-Mohand, Maurice Medebielle
1Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA.
Organic Letters
|December 20, 2002
Abstract:
[reaction: see text] A novel method for highly regioselective and stereospecific nucleophilic trifluoromethylation of vicinal diol cyclic sulfates, using the reagent derived from reduction of trifluoromethyl iodide by tetrakis(dimethylamino)ethylene (TDAE), is presented.