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Alignment control of a cyanine dye using a mesoporous silica film with uniaxially aligned mesochannels
Ayumu Fukuoka1, Hirokatsu Miyatab, Kazuyuki Kuroda
1Department of Applied Chemistry, Waseda University, 3-4-1 Ohkubo, Shinjuku-ku, Tokyo 169-8555, Japan.
Abstract:
The feasibility of alignment control of low-molecular-weight guest species by controlling the orientation of mesochannels in a mesoporous silica host has been shown for the first time; spectroscopically anisotropic absorption behaviour of a cyanine dye was observed upon its incorporation into the mesochannels of a mesoporous silica film with uniaxially aligned porous structure, proving that the preferred alignment of the dye molecules was achieved on a macroscopic scale.