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Helical templating of polyiodide networks at a binuclear metallo complex
Caitlin J Horn1, Alexander J Blake, Neil R Champness
1School of Chemistry, The University of Nottingham, University Park, Nottingham, UK NG7 2RD.
Chemical Communications (Cambridge, England)
|March 5, 2003
Abstract:
A homobimetallic supramolecular helicate has been prepared from a new multimodal ligand, and used to template the formation of two polyiodide networks, one containing an unprecedented figure-of-eight polyiodide helix, the other dominated by peripheral C-H...I polyiodide chain interactions.